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Ministry of Gossip
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2014 Met Ball couples | Ryan Reynolds and Blake Lively

Reynolds met the "Gossip Girl" star on the set of 2011's "The Green Lantern," and the pair wed in September 2012. He wore a velvet tux by Gucci and Lively wore a glittery dress by the Italian fashion house at the May 5 high-profile fashion parade.Timothy A. Clary / AFP / Getty Images