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8. Xenia Onatopp
Appearances: Xenia Onatopp was played by Famke Janssen in 1995's "Goldeneye," Pierce Brosnan's 007 debut.
Honcho or henchman? Henchwoman, working for Alec Trevelyan, leader of the Janus crime syndicate and a former MI6 agent and friend to Bond. Onatopp is a former KGB fighter pilot and assassin -- skills that come in handy in her work for Janus.
Dastardly distinction: Most memorable is her predilection for sadomasochistic pleasure in assassinating her enemies. She crushes her enemies with her steely thighs during sex and takes pleasure in their physical attacks on her.