Where you've seen her: You either laugh, cheer her on or both while watching her as Mrs. Smith on "Mr.and Mrs. Smith" Why we love her: As much as she loves kids, we should love her for that alone. She's the right-hand woman of actor Brad Pitt, but she is a business woman and philanthropist all her own. Outside of acting, her charity work includes UNICEF, ONE Campaign and UNHCR.
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