Best all-star pairing

Kimberly Williams-Paisley
Carrie Underwood and Brad Paisley couldn’t have been any more adorable together during their duet of the late Eddy Arnold’s “Make the World Go Away.” But don’t get any ideas. Brad is married to Kimberly Williams-Paisley from “Father of the Bride.” Brad thanked Kimberly when accepting the... Mark J. Terrill / Associated Press
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