Los Angeles Times

Linda Hamilton as Mary Bartowski

First seen in: "Chuck vs. the Anniversary" "Chuck" has built up a mythology over the years that Chuck Bartowski was in a lot of ways destined to lead the life of a spy -- and the introduction of Mary Bartowski filled in a huge piece of that puzzle. That Hamilton could play a ruthless secret agent was no surprise at all -- but the fact that she handled the show's lighter moments so well too made Mary a great addition to Team Bartowski. NBC
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