Los Angeles Times

'Gossip Girl' (The CW)

Premieres: Monday, Sept. 14 Expect to See: The upperclassmen are off to college, which means Manhattan will truly become their playground. But while Blair ( Leighton Meester) and Chuck ( Ed Westwick) are busy "celebrating" their couple-dom, Serena ( Blake Lively) is giving Carter Baizen (Sebastian Stan) another shot and Nate ( Chace Crawford) is getting to know a new girl (Joanna Garcia), poor little Jenny's still battling the mean girls back at Constance. Also, look for the return of Georgina ( Michelle Trachtenberg) who's got her paws on Dan once again. Not to worry though, it won't last, as we're hearing the young Humphrey has a fling with an NYU freshman ( Hilary Duff) on tap too. Related: 10 reasons to love 'Gossip Girl's' Dorota Zap2it's Fall TV preview The CW